2023 Nanotechnology 34 365705, 19 June 2023 DOI 10.1088/1361-6528/acd9d2

Direct Visualization of Nanoparticle Morphology in Thermally Sintered Nanoparticle Ink Traces and the Relationship Among Nanoparticle Morphology, Incomplete Polymer Removal, and Trace Conductivity


Ghansham Rajendrasingh Chandel5,1, Jiayue Sun5,2, Sai Ankit Etha1, Beihan Zhao1, Vishal Sankar Sivasankar1, Shakiba Nikfarjam3, Mei Wang3, Daniel R Hines4, Abhijit Dasgupta1, Taylor Woehl3, and Siddhartha Das1
1 Department of Mechanical Engineering, University of Maryland, College Park, MD 20742, United States of America
2 Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, United States of America
3 Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD 20742, United States of America
4 Laboratory for Physical Sciences, 8050 Greenmead Drive, College Park, MD 20740, United States of America
5 Contributed equally.

For more information about this article and related research, please contact Prof. Siddhartha Das and Prof. Abhijit Dasgupta.

Abstract:

A key challenge encountered by printed electronics is that the conductivity of sintered metal nanoparticle (NP) traces is always several times smaller than the bulk metal conductivity. Identifying the relative roles of the voids and the residual polymers on NP surfaces in sintered NP traces, in determining such reduced conductivity, is essential. In this paper, we employ a combination of electron microscopy imaging and detailed simulations to quantify the relative roles of such voids and residual polymers in the conductivity of sintered traces of a commercial (Novacentrix) silver nanoparticle-based ink. High resolution transmission electron microscopy imaging revealed details of the morphology of the inks before and after being sintered at 150 °C. Prior to sintering, NPs were randomly close packed into aggregates with nanometer thick polymer layers in the interstices. The 2D porosity in the aggregates prior to sintering was near 20%. After heating at 150 °C, NPs sintered together into dense aggregates (nanoaggregates or NAgs) with sizes ranging from 100 to 500 nm and the 2D porosity decreased to near 10%. Within the NAgs, the NPs were mostly connected via sintered metal bridges, while the outer surfaces of the NAgs were coated with a nanometer thick layer of polymer. Motivated by these experimental results, we developed a computational model for calculating the effective conductivity of the ink deposit represented by a prototypical NAg consisting of NPs connected by metallic bonds and having a polymer layer on its outer surface placed in a surrounding medium. The calculations reveal that a NAg that is 35%–40% covered by a nanometer thick polymeric layer has a similar conductivity compared to prior experimental measurements. The findings also demonstrate that the conductivity is less influenced by the polymer layer thickness or the absolute value of the NAg dimensions. Most importantly, we are able to infer that the reduced value of the conductivity of the sintered traces is less dependent on the void fraction and is primarily attributed to the incomplete removal of the polymeric material even after sintering.

The article is available online here.


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